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You'd do this via bill payment, aka bpay.
That's how I've paid existing VISA Gold statements, and how I intend to pay for future CitiGold statements. Usually the payment clears overnight (as a payment received that day), so I try to pay a day or two before the due date.
I hope that Citi processes internet banking payments as received the same day it is paid (if paid before 4PM).
The only annoyance is NAB's requirement to get SMS notification for payments above a certain amount ($2500?), whichmakes for a noisy internet bannking payment :evil: .
Generally if you use one credit card to pay another credit card bill, the paying card treats the payment as a cash advance and you are charged fees and interest accordingly. Does not matter if using BPay or any other form of paying the bill from another credit card.