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I haven't done the overnight flight - I usually take the daytime via Ayers Rock, which means you do lose a day travelling though and there is no business class and the flights to the centre can get quite full.
i took the sunday flights september last year and both there and back were about 60% full (we had three seats for two of us). being, you'd assume, a predominantly leisure route your chances of an upgrade would be reasonable due to a relative lack of business travellers, except for the fact it's a 737 so there's not many seats to upgrade to. and the seats that you do upgrade to aren't that much better than a normal economy one anyway...
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