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Thanks Ewing. We weren't sure whether the international or domestic check in times applied.
Allowing yourself a bit more time is better. Is the time they will be checking in a busy or quiet time?
Some people cut things way too fine which may work if everything's okay but if they arrive right on flight close & there's an issue with the booking eg TA hasn't issued ticket they're up the creek.
Usually these people have booked themselves a one hour connection in SYD so no leeway to get later dom flight that will still make the intl connection.
If your colleague can OLCI at least you know there are no ticketing issues so they only need to do the bag drop.